Does Refrigerant Get Old or Wear Out?

Over the years, I have heard technicians say that refrigerant can wear out or “lose its blend” by sitting in a tank.

This does not happen… at least not like that.

What can and does happen is called “fractionation.” Refrigerant blends are composed of a mix of refrigerants with different vapor and liquid PT characteristics, known as azeotropic, zeotropic, or in some cases, near-azeotropic. Those are all fancy words to mean that these refrigerant blends must be added or removed completely or in the liquid state to prevent more or less of one refrigerant in the mix from being added or removed than the other. If the refrigerant is allowed to fractionate, and some of it is added in the vapor-only state, both the refrigerant left in the tank and the refrigerant added to the system will no longer have the designed properties of the listed refrigerant.

If one of the refrigerants in the blend leaks out faster, what you have left isn't the same refrigerant.

While all blends should all be charged in the liquid state, some refrigerants are more likely to be impacted by fractionation than others.

For example, R-410a  (50% R-32 & 50% R-125) has very little “glide” between liquid and vapor, and so while it is a blend, it is less likely to fractionate severely when charged in the vapor phase (which you still shouldn't do).

A refrigerant like R-407c (a mixture of R32/125/134a) will fractionate much more easily, resulting in far greater pressure/temperature swings and poor performance when it occurs.

Fractionation will often happen for three reasons:

  1. A technician charged the system in the vapor phase (tank upright) instead of in the liquid phase (upside down).
  2. The tank had a small leak while stored upright.
  3. The system has a significant leak.

The particular case of fractionation being caused by a system leak depends on many factors, including what part of the system the leak occurs, the physical location of the leak, and how much refrigerant leaked out. A study done at Purdue shows that fractionation after leakage can be a factor in high-glide systems like R407c.

The ramifications of this depend on the specific situation, but in some cases, the only viable option will be to recover completely and recharge with a virgin charge. That is not because refrigerant has “lost its mix” from sitting, but rather because some of the”mix” has left the tank or system at a different rate, leaving an improper mix behind.


P.S. – If you want to learn more about glide, check out this article.

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3 responses to “Does Refrigerant Get Old or Wear Out?”

  1. Considering this, do you recomend storing containers upside down? I have seen some people do this.

    I always weigh my bottles before first use. I have gotten some that are a couple pounds short and I worry that there has blend a leak and there was fractionation.

  2. Old techs wear out, leak, and change states, look at the guy at 20, then look at him at 65! Time ravages everything…

  3. Interesting article, It also came to mind as Justin has asked, storing containers inverted, if this might prohibit unintended release of the contents.

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